To create another domain just click on the Add Domain button:

If the button does not appear it means that you have reached your additional domain limit on web hosting.

Then complete the fields with the information of your choice: domain name, location of the website files, root directory and if you want to activate SSL Let's Encrypt on it :

By default Plesk creates a subfolder named after the new domain on your FTP server. If you want to point your additional domain to the same folder as the main domain just empty the Document Root field.

You will receive a message confirming the addition of the domain :

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